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So far, all the aromatic compounds you have seen have been hydrocarbons. However, most aromatic systems are heterocyclic—that is, they contain atoms other than just carbon and hydrogen. (In fact, the majority of all organic compounds are aromatic heterocycles!) A simple example is pyridine, in which a nitrogen replaces one of the CH groups of benzene. The ring still has three double bonds and thus six π electrons. Consider the structure shown on the left, pyrrole. This is also aromatic but it’s not enough just to use the electrons in the double bonds: in pyrrole the nitrogen’s lone pair contributes to the six π electrons needed for the system to be aromatic. Aromatic chemistry makes several more appearances in this book: in Chapter 21 we shall look at the chemistry of benzene and in Chapters 30 and 31 we shall discuss heterocyclic aromatic compounds in much more detail.
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